I'll definitely get homemade Spider-Man & Vulture and Spidey & Shocker. It's a shame Shocker doesn't look more like the leaked set photo, but the rest look great.
I'm not as sure about the other sets, though. Peter looks good, but I don't really need ToMay. Tinkerer is unsurprisingly just a civilian, so I think I'll be able to skip that set.